Synthesis and Characterization of Zno Nanoparticles Using Hydrothermal and Sol-Gel Techniques for Dye-Sensitized Solar Cells

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H. Musleh N. AlDahoudi H. Zayed S. Shaat H. M. Tamous N. Shurrab A. Issa J. Asad

Abstract

ZnO nanoparticles (ZnO NPs) were synthesized using hydrothermal and sol-gel techniques using zinc acetate dihydrate (Zn (CH3COO)2.2H2O) as a row material and methanol as a solvent. The structural properties of ZnO NPs were studied using EDX, XRD, TEM, and the optical properties were characterized using UV-VIS and PL spectroscopies. The synthesized ZnO NPs showed high purity and revealed a wurtzite (hexagonal) crystal structure with particle size (D) ranged from 25 nm to 28 nm. The UV-VIS absorption spectra of ZnO NPs samples and sensitizing dyes were performed. The obtained ZnO NPs exhibited the direct optical bandgap 3.15 eV. Dye-sensitized solar cells (DSSCs) were fabricated using synthesized ZnO NPs as a semiconducting layer, which was dyed with different low cost dyes such as Eosin B (EB), Eosin Y (EY) and Rhodamine B (RB) that was used to sensitize the photoanode (ZnO NPs). The experimental results showed a significant efficiency for the fabricated DSSCs of synthesized ZnO NPs via sol gel technique comparing to hydrothermal technique. The EY dye exhibited the best performance among others, where a conversion efficiency showed a noteworthy improvement from 0.12 to 1.08 %.

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How to Cite
[1]
H. Musleh, “Synthesis and Characterization of Zno Nanoparticles Using Hydrothermal and Sol-Gel Techniques for Dye-Sensitized Solar Cells”, JUBES, vol. 26, no. 9, pp. 256 - 267, Nov. 2018.
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